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Evaporation Tables & Crucible Recommendations

EVAPORATION
MATERIAL
TEMPERATURE (șC)
@ VAP. PRESSURE
EVAPORATION TECHNIQUES REMARKS
n = Index
of Refraction
10-8
TORR
10-6
TORR
10-4
TORR
ELECTRON
BEAM
CRUCIBLE COIL BOAT
Titanium
Monoxide (TiO)
-1500 Good Vit. Carbon W Mo Use gentle preheat to outgas. Films TiO2 if evaporated like TiO2; n = 2.2
Titanium
Nitride (TiN)
Good Mo Sputtering preferred. Decomposes with thermal evaporation.
Titanium
Sesquioxide (Ti2O3)
Good W Decomposes.
Tungsten (W) 2117 2407 2757 Good Forms volatile oxides. Films hard & adherent.
Tungsten
Boride (WB2)
Poor
Tungsten
Carbide (W2C)
1480 1720 2120 Excel. C
Tungsten
Telluride (WTe3)
Quartz
Tungsten
Trioxide (WO3)
980S Good W Pt Use gentle preheat to outgas. W reduces oxide slightly. n = 1.68
Uranium (U) 1132 1327 1582 Good W Mo W Films oxidize.
Uranium
Carbide (UC2)
2100 Carbon Decomposes.
Uranium
Dioxide (UO2)
W Ta causes decomposition.
Uranium
Fluoride (UF4)
300 Ni
Uranium
Oxide (U3O8)
W Decomposes at 1300șC to UO2.
Uranium
Phosphide (UP2)
1200 Ta Decomposes.
Uranium
Sulphide (U2S3)
1400 W Slight decomposition.
Vanadium (V) 1162 1332 1547 Excel. W Mo Wets Mo. EB evaporated films preferred.
Vanadium
Carbide (VC)
-1800
Vanadium
Dioxide (VO2)
-575S Deposit metal in 1 x 10-3O2 JVST A2(2) 301 (1984)
Vanadium
Pentoxide (V2O5)
-500 Quartz
Ytterbium (Yb) 520S 590S 690S Good Ta
Ytterbium
Fluoride (YbF3)
-800 Mo n = 1.57 @ 3.8”
Ytterbium
Oxide (Yb2O3)
-1500S Ir Loses oxygen.
Yttrium (Y) 830 973 1157 Excel. Al2O3 W W Ta High Ta solubility.
Yttrium
Aluminum
Oxide (Y3Al5O12)
Good W Films not ferroelectric.
Yttrium
Oxide (Y2O3)
-2000S Good C W Loses oxygen, films smooth and clear. n = 1.79 @ 1”
Zinc (Zn) 127 177 250 Excel. Al2O3
Quartz
W Mo W
Ta
Evaporates well under wide range of conditions.
Zinc
Bromide (ZnBr2)
-300 Carbon W Decomposes.
Zinc
Fluoride (ZnF2)
-800 Quartz Pt Ta
Zinc
Nitride (Zn3N2)
Mo Decomposes.
Zinc
Oxide (ZnO)
-1800 Fair Anneal in air at 450șC to reoxidize; n = 2.0 JVST 12, 879 (1975)
Zinc
Selenide (ZnSe)
660 Quartz W Mo Ta W
Mo
Use gentle preheat to outgas. Evaporates well. n = 2.6
Zinc
Sulphide (ZnS)
-800S Good Ta Mo Use gentle preheat to outgas. Films partially decompose. Sticking coefficient varies with substrate temperature. n 2.3 @ .5”
Zinc
Telluride (ZnTe)
-600 Mo Ta Use gentle preheat to outgas. n = 2.85 @ .5”
Zinconium
Nitride (ZrN)
Reactively evaporate in 10-3 N2 atmosphere.
Zirconium
Oxide (ZrO2)
-2200 Good W Films oxygen deficient, clear and hard. n = 2.05 @ .75”
Zirconium
Silicide (ZrSi2)

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Key:
S = Sublime
D = Decomposes
Excel. = Excellent



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