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Evaporation Tables & Crucible Recommendations

EVAPORATION
MATERIAL
TEMPERATURE (ºC)
@ VAP. PRESSURE
EVAPORATION TECHNIQUES REMARKS
n = Index
of Refraction
10-8
TORR
10-6
TORR
10-4
TORR
ELECTRON
BEAM
CRUCIBLE COIL BOAT
Sulphur (S8) 13 19 57 Poor Quartz W Poisons vacuum system.
Supermalloy (Ni/Fe/Mo) Good Sputtering preferred; or co-evaporate from 2 sources, Permalloy and Mo.
Tantalum (Ta) 1960 2240 2590 Excel. Forms good films.
Tantalum
Carbide (TaC)
-2500 JVST 12, 811 (1975)
Tantalum
Nitride (TaN)
Reactive; evaporate Ta in 10-3 N2.
Tantalum
Pentoxide (Ta2O5)
1550 1780 1920 Good Vit. Carbon W Ta Slight decomposition; evaporate in 10-3 Torr of O2. n = 2.0 @ 1.5µ App. Opt. 19, 1837 (1980)
Technetium (Tc) 1570 1800 2090
Teflon (PTFE) W Baffled source. Film structure doubtful.
Tellurium (Te) 157 207 277 Poor Al2O3
Quartz
W W Ta Wets w/o alloying. Toxic.
Terbium (Tb) 800 950 1150 Excel. Al2O3 Ta
Terbium
Fluoride (TbF3)
-800
Terbium
Oxide (Tb2O3)
1300 Ir Partially decomposes.
Terbium
Oxide (Tb4O7)
Ta Films TbO.
Thallium (Tl) 280 360 470 Poor Al2O3
Quartz
W Ta Wets freely, very toxic.
Thallium
Bromide (TlBr)
-250S Quartz Ta Toxic n = 2.3
Thallium
Chloride (TlCl)
-150S Quartz Ta Toxic n = 2.25
Thallium
Iodide (TlI)
-250S Quartz Toxic n = 2.78
Thallium
Oxide (Tl2O3)
350 Toxic, Goes to Tl2O @ 850ºC.
Thorium (Th) 1430 1660 1925 Excel. W W Ta
Mo
Toxic, radioactive.
Thorium
Bromide (ThBr4)
S S S Mo Toxic n = 2.47 @ 5µ
Thorium
Carbide (ThC2)
-2300 Carbon Radioactive.
Thorium
Dioxide (ThO2)
-2100 Good W Radioactive. n = 1.86 at 2.2 microns
Thorium
Fluoride (ThF4)
-750 Fair Vit. Carbon Mo Radioactive. n = 1.52 Heat substrate to above 150ºC. JVST 12, 919, (1975)
Thorium
Oxyfluoride (ThOF2)
Mo Ta Radioactive. n = 1.52
Thorium
Sulphide (ThS2)
Sputtering preferred; or co-evaporate from 2 sources.
Thulium (Tm) 461S 554 680 Good Al2O3 Ta
Thulium
Oxide (Tm2O3)
1500 Ir Decomposes.
Tin (Sn) 682 807 997 Excel. Al2O3 W Mo Wets Mo; use Ta liner in Eb guns.
Tin
Oxide (SnO2)
-1000S Excel. Quartz
Al2O3
W W Films from W oxygen deficient, oxidize in air. n = 2.0
Tin
Selenide (SnSe)
-400 Good Quartz JVST 12, 110 (1975)
Tin
Sulphide (SnS)
-450 Quartz
Tin
Telluride (SnTe)
-450 Quartz
Titanium (Ti) 1067 1235 1453 Excel. TiC W Alloys with refractory metals; evolves gas on first heating.
Titanium
Bromide (TiB2)
Poor
Titanium
Carbide (TiC)
-2300 JVST 12, 851, (1975)
Titanium
Dioxide
(rutile) (TiO2)
-1300 Fair W Mo Evaporate in 10-4 of O2 onto 350º substrates. n = 2.4 App. Opt. 15, 2986 (1976)

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Key:
S = Sublime
D = Decomposes
Excel. = Excellent



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