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Evaporation Tables & Crucible Recommendations

EVAPORATION
MATERIAL
TEMPERATURE (ºC)
@ VAP. PRESSURE
EVAPORATION TECHNIQUES REMARKS
n = Index
of Refraction
10-8
TORR
10-6
TORR
10-4
TORR
ELECTRON
BEAM
CRUCIBLE COIL BOAT
Rhenium Oxide (Re2O2) - 100
Rhodium (Rh) 1277 1472 1707 Good ThO2 Vit Carbon W W EB gun preferred
Rubidium (Rb) - 3 37 111 Quartz
Rubidum Chloride (RbCl) - 550 Quartz n = 1.49
Rubidium Iodide (RbI) - 400 Quartz
Ruthenium (Ru) 1780 1990 2260 Poor W Spits violently in EB. Requires degas.
Samarium (Sm) 373 460 573 Good Al2O3 Ta
Samarium Oxide (Sm2O3) Good ThO2 Ir Loses O2. Films smooth, clear.
Samarium Sulphide (Sm2S3) Good AIP Conf. Proc. on Mag. & Mag. Mat. B, 5, 860 (1971)
Scandium (Sc) 714 837 1002 Excel. Al2O3BeO W Alloys with Ta
Scandium Oxide (Sc2O3) - 400 Fair Loses oxygen. n = 1.88 @ 5µ
Selenium (Se) 89 125 170 Good Al2O3 Vit. Carbon W Mo W Mo Toxic. Poisons vacuum systems. JVST 9, 387 (1972); 12, 573 & 807 (1975)
Silicon (Si) 992 1147 1337 Fair BeO Ta Vit. Carbon W Ta Alloys with W; use heavy W boat. SiO produced above 4 x 10-6 Torr. EB best. n = 3.42 App. Opt. 15, 2348 (1976)
Silicon Boride (SiB6) Poor
Silicon Carbide (SiC) 1000 Sputtering preferred.
Silicon Dioxide (SiO2) - 1025 Excel. Al2O3 Quartz Excel. in EB. n = 1.47
Silicon Monoxide (SiO) - 850 S Fair Ta W Ta Baffle box source best for resistance evaporation. Low rate suggested. n = 1.6
Silicon Nitride (Si3N4) - 800 n = 2.1
Silicon Selenide (SiSe) 550 Quartz
Silicon Sulphide (SiS) 450 Quartz
Silicon Telluride (SiTe2) 550 Quartz
Silver (Ag) 847 958 1105 Excel. Al2O3 Mo W Ta Mo Evaporates well from any source.
Silver Bromide (AgBr)) - 380 Quartz Ta n = 2.25
Silver Chloride (AgCl) - 520 Quartz Mo Pt n = 2.07
Silver Iodide (AgI) - 500 Ta n = 2.21
Sodium (Na) 74 124 192 Quartz Ta S.S. Use gentle preheat to outgas. Metal reacts violently in air.
Sodium Bromide (NaBr) - 400 Quartz Use gentle preheat to outgas. n = 1.64
Sodium Chloride (NaCl) 530 Good Quartz Ta W Mo Cu ovens, little decomposition. Use gentle preheat to outgas. n = 1.54
Sodium Cyanide (NaCN) - 550 Ag Use gentle preheat to outgas. n = 1.45
Sodium Fluoride (NaF) - 700 Good BeO Mo Ta W Use gentle preheat to outgas. No decomposition. n = 1.30 @ 55µ
Sodium Hydroxide (NaOH) - 470 Pt Use gentle preheat to outgas. n = 1.36
Spinel (MgO35Al2O3) Good n = 1.72
Strontium (Sr) 239 309 403 Poor Vit. Carbon W W Ta Mo Wets but does not alloy with refractory metals. May react violently in air.
Strontium Fluoride (SrF2) - 1000 Al2O3 n = 1.44
Strontium Oxide (SrO) 1500 S Al2O3 Mo Reacts with Mo and W; n = 1.87
Strontium Sulphide (SrS) Mo Decomposes. n = 2.11

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Key:
S = Sublime
D = Decomposes
Excel. = Excellent



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