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Evaporation Tables & Crucible Recommendations

EVAPORATION
MATERIAL
TEMPERATURE (șC)
@ VAP. PRESSURE
EVAPORATION TECHNIQUES REMARKS
n = Index
of Refraction
10-8
TORR
10-6
TORR
10-4
TORR
ELECTRON
BEAM
CRUCIBLE COIL BOAT
Lead
Iodide (PbI2)
-500 Quartz Pt n = 2.7 J. Opt. Soci. 65, 914
Lead
Oxide (PbO)
-550 Quartz
Al2O3
Pt No decomposition. n = 2.55
Lead
Stannate (PbSnO3)
670 780 905 Poor Al2O3 Pt Disproportionates.
Lead
Selenide (PbSe)
-500S Graphite
Al2O3
W Mo
Lead
Sulphide (PbS)
550S Quartz
Al2O3
W Little decomposition. n = 3.91
Lead
Telluride (PbTe)
780 910 1050 Al2O3
Graphite
Mo Pt
Ta
Vapors toxic. Deposits Te rich. Sputtering preferred, or co-evaporate from sources. n = 5.6 @ 5”
Lead
Titanate (PbTiO3)
Ta
Lithium (Li) 227 307 407 Good Al2O3
BeO
Ta
S.S.
Metal reacts violently in air.
Lithium
Bromide (LiBr)
-500 Ni n = 1.78
Lithium
Chloride (LiCl)
400 Ni Use gentle preheat for outgas. n = 1.66
Lithium
Fluoride (LiF)
875 1020 1180 Good Al2O3 Ni, Ta
Mo W
Rate control important for optical films. Use gentle preheat for outgas. n = 1.36. J. Appl. Opt. 11, 2245 (1972)
Lithium
Iodide (LiI)
400 Mo W
Lithium
Oxide (Li2O)
850 Pt Ir n = 1.64
Lutetium (Lu) 1300 Excel. Al2O3 Ta
Lutetium
Oxide (Lu2O3)
1400 Ir Decomposes.
Magnesium (Mg) 185S 247S 327S Good Al2O3
Vit. Carbon
W W Mo
Ta, Cb
Extremely high rates possible.
Magnesium
Aluminate (MgAl2O4)
Good Natural spinel.
Magnesium
Bromide (MgBr2)
-450 Ni Decomposes.
Magnesium
Chloride (MgCl2)
400 Ni Decomposes. n = 1.6
Magnesium
Fluoride (MgF2)
1000 Excel. Al2O3 Mo Ta Rate control and substrate heat important for optical films. n = 1.38 J. Appl. Opt. 11, 2245 (1972)
Magnesium
Iodide (MgI2)
200 Ir
Magnesium
Oxide (MgO)
1300 Good Carbon
Al2O3
W produces volatile oxides. n = 1.7 J. Appl. Opt. 11, 2243 (1972)
Manganese (Mn) 507S 572S 647S Good Al2O3
BeO
W W Ta
Mo
Manganese
Bromide (MnBr2)
500 Inconel
Manganese
Chloride (MnCl2)
450 Inconel
Manganese
Oxide (Mn3O4)
W
Manganese
Sulphide (MnS)
1300 Mo Decomposes. n = 2.7
Mercury (Hg) -68 -42 -6
Mercury
Sulphide (HgS)
250S Al2O3 Decomposes.
Molybdenum (Mo) 1592 1822 2117 Excel. Films smooth, hard. Careful degas req'd.
Molybdenum
Boride (MoB2)
Poor
Molybdenum
Carbide (Mo2C)
Fair Evaporation of Mo(Co)6 yields Mo2C.
Molybdenum
Disulphide (MoS2)
-50
Moylbdenum
Silicide (MoSi2)
W Decomposes.
Molybdenum
Trioxide (MoO3)
-900 Al2O3
BN
Mo Pt Slight O2 loss. n = 1.9
Neodynium (Nd) 731 871 1062 Excel. Al2O3 Ta Low Ta solubility.

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Key:
S = Sublime
D = Decomposes
Excel. = Excellent



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